Abstract: MATH/CHEM/COMP 2002, Dubrovnik,
June 24-29, 2002
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Pearson-type I Distribution Function for Polydisperse Polymer
Systems. Molecular Mass Distribution
Grozdana BogdaniC1 and Lajos Jakab2
1INA - Industrija nafte, d.d., Strategic Development, Research and
Investment Sector, Lovinciceva b.b., 10002 Zagreb, POB 555, Croatia 2Formerly KFKI, Atomic Energy Research
Institute, H 1525 Budapest, Hungary An attractive feature of the
distribution function, which uses relatively simple expression for
approximating probability density, is presented. The Pearson-type I distribution
function is used to represent the molecular mass distribution (MMD) function
for polymers for which the number average, , weight average, , z-average, , and z+1 average, , values are available. Consequently, estimations of the
different molecular mass average values (i.e. , , and , respectively), are performed from experimentally
determined MMD, proposing the Pearson-type I function as a model MMD
function, fitting the model parameters and using nonlinear regression. |